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Zeitschrift für Materialwissenschaften und Ingenieurwesen

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Photoluminescence Spectrum of PbO-NaF-B2O3 Glass Doped with Ln3+ (Sm3+/Ho3+) Ions

Abstract

N. Narasimha Rao*, B. J.R.S.N. Swamy, P. Raghava Rao, P. Naresh and A. Chitti Babu

Ln2O3 doped PbO-NaF-B2O3 glasses were prepared and characterized through spectroscopic technique such as photoluminescence at room temperature to derive luminescence properties of Ln3+ ions in these glasses. Radiative properties which include radiative transition possibilities, branching ratios, radiative lifetime and stimulated emission cross sections of the fluorescent degree of Ln3+ ions in titled glasses are determined. In the present work all our systematic analysis has been presented with an example of results obtained in PbO-NaF-B2O3-Ln2O3 glasses. These results are used to access the gain media and in turn useful not only to write waveguides but also to modify the fluorescence properties through laser irradiation.

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